WebTris (trimethylsilyl)silane, TTMSS. Tributyltin hydride is the reagent of the choice for the reduction of functional groups after a radical mechanism. But organotin compounds are toxic and can sometimes only be separated laboriously from nonpolar reaction products. It was necessary to find new reagents which made the adaption of these radical ... Web688-73-3. tri-n-butyl-tin hydride. Conditions. Yield. In tetrahydrofuran byproducts: 1-naphthylboronic acid; to srirred soln. of Sn-compound in THF was added soln. of BH3 in THF under N2, mixt. was left at room temp. for 1 h, refluxed for 3 h, cooled, Et2O and water was added; dried with MgSO4, solvent was removed under vac., column chromy. on ...
hydride - offers from hydride 製造商, 供應商, 出口商, 批發商 & 分銷 …
Web开馆时间:周一至周日7:00-22:30 周五 7:00-12:00; 我的图书馆 WebReducing agent and source of tributyltin radicals. Widely used for selective reduction of alkyl halides to alkanes by a radical chain mechanism. The reaction is tolerant of a wide range of functionality, including OH and NH, in contrast to polar metal hydride reagents. For reviews, see: Synthesis, 499 (1970); 665 (1987). thermostat\\u0027s u2
检索结果-暨南大学图书馆
WebOct 2, 2014 · Product Name Tri-n-butyltin hydride Cat No. : AC215730000; AC215730100; AC215730500; AC215732500 CAS No 688-73-3 Synonyms Tributylstannane; Tributyltin; Tributylstannic hydride. Recommended Use Laboratory chemicals. Uses advised against Food, drug, pesticide or biocidal product use. Details of the supplier of the safety data sheet WebDec 6, 2024 · Tributyltin Hydride Iupac Name:tributyltin CAS No.: 688-73-3 Molecular Weight:291.066 Modify Date.: 2024-12-06 15:05 Introduction: Tributyltin hydride (TBTH) is as a reagent for the reductive ionic 1,5-cyclization of 3-azamuconoates (3-azahexa-2,4-dienedioates).Tributyltin hydride can also mediate cyclisation of unsaturated ethers and … WebApplication: Tributyltin hydride is a reducing agent acting by radical intermediates. CAS Number: 688-73-3. Purity: ≥95%. Molecular Weight: 291.06. Molecular Formula: C 12 H 28 … thermostat\u0027s u1